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- W2949667037 abstract "In the past few years, considerable development has taken place in the field of f-element organometallics (1, 2, 3), highly representative examples cited being usually complexes involving one singular ligand (homoleptic organometallics), e.g. (C5H5)nfM with n = 2-4, [(C8H8)2fM]q (q = 0 or - 1), [Li(tmed)]3[Ln(CH3)6] (4) and [(CH3)2P(CH2)2]3fM (5). Although extensive studies of such compounds undoubtedly have their merits apart from purely aesthetic aspects, it is almost exclusively the much wider field of mixed-ligand systems that provides valuable information wherever chemistry with f-organometallics is concerned. Thus it is well-documented that various organo-uranium compounds can catalyze the stereospecific formation of cis-1,4-polybutadienes from 1,3-butadiene (6) in which homogeneous process complexes with organic ligands are highly superior to classical oxides or halides. Although well-defined organo-uranium complexes such as (C5H5)3UX and (C3H5)4U/Lewis acid, respectively, have been reported to be most most efficient, the (unknown) catalytically active species will undoubtedly be a mixed-ligand system" @default.
- W2949667037 created "2019-06-27" @default.
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- W2949667037 date "1980-09-23" @default.
- W2949667037 modified "2023-09-26" @default.
- W2949667037 title "Synthesis and Spectroscopy of Novel Mixed-Ligand Organolanthanide Complexes" @default.
- W2949667037 doi "https://doi.org/10.1021/bk-1980-0131.ch004" @default.
- W2949667037 hasPublicationYear "1980" @default.
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