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- W2949667910 abstract "When treated with t-butyl hypochlorite and pyridine in methylene dichloride, secondary alcohols give the corresponding ketones in very high yield. The relative reactivities of a number of p-substituted 1-phenylethanols containing electron-donating and -withdrawing substituents were investigated. Oxidation of cis- and trans-4-t-butylcyclohexanol, as well as some other cycloalkanols, proceeds with the same relative rate. On the basis of this and other data a cyclic transition state and loss of α-hydrogen of the starting alcohol as hydride ion are proposed as characteristics of the reaction mechanism." @default.
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- W2949667910 date "1988-07-26" @default.
- W2949667910 modified "2023-09-26" @default.
- W2949667910 title "ChemInform Abstract: Oxidation of Secondary Alcohols with t-Butyl Hypochlorite in the Presence of Pyridine." @default.
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- W2949667910 doi "https://doi.org/10.1002/chin.198830113" @default.
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