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- W2949673860 abstract "The structure of long known Xe(OTeF5)4 is established by x-ray crystallography. The xenon atom is surrounded by four equidistant oxygen atoms in a square planar manner. O2Xe(OTeF5)2 is formed according to OXe(OTeF5)4 → O2Xe(OTeF5)2 + F5TeOTeF5, Its structure, again established by x-ray crystallography, shows a very distorted tetrahedral or pseudo-trigonal bipyramidal xenon environment. The electron pair repulsion models fails here in explaining the details of this geometry. Strukturen von Xenon-Sauerstoff-Verbindungen Die Struktur des lange bekannten Xe(OTeF5)4 wurde durch die Kristallstrukturanalyse aufgeklärt. Das Xenonatom ist von vier Sauerstoffatomen in einer regelmäßigen quadratisch planaren Anordnung umgeben. O2Xe(OTeF5)2 ensteht gemäß O Xe(OTeF5)4 → O2Xe(OTeF5)2 + F5TeOTeF5. Die Struktur—wiederum mit Hilfe der Röntgenstrukturanalyse bestimmt—zeigt das Xenonatom in einer sehr verzerrten tetraedrischen oder pseudo-trigonal bipyramidalen Umgebung. Das Elektronenpaarabstoßungsmodell versagt hier bei der Erklärung der Feinheiten dieser Struktur." @default.
- W2949673860 created "2019-06-27" @default.
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- W2949673860 date "1992-03-01" @default.
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- W2949673860 title "Structures of Xenon Oxygen Compounds" @default.
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