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• W2949675129 abstract "We find that GeIV substitutes cleanly for AlIII at the central tetrahedral site in the AlO4Al12(OH)24(OH2)127+ polyoxocation, creating a GeO4Al12(OH)24(OH2)128+ cation with some slight structural distortion, but a structure that overall still resembles an ε-Keggin molecule. These substituted aluminum polyoxo molecules are important because they resemble structural fragments at the surface of common aluminum (hydr)oxide minerals and can be used to study in detail the kinetics of oxygen exchanges with bulk solution." @default.
• W2949675129 created "2019-06-27" @default.
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• W2949675129 date "2001-07-04" @default.
• W2949675129 modified "2023-09-27" @default.
• W2949675129 title "Synthesis and Characterization of the GeO₄Al₁₂(OH)₂₄(OH₂)₁₂⁸⁺ Polyoxocation" @default.
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• W2949675129 doi "https://doi.org/10.1021/ic010146e" @default.
• W2949675129 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11487360" @default.
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