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- W2949675865 abstract "Abstract A synthesis of (±)-Mitomycin K has been achieved in thirteen steps from commerically available 2,5-dimethylanisole in a 1.36% overall yield. One of the key steps is the oxidation of the C9-9a double bond of 1 by (hexamethylphosphoramido)oxodiperoxomolybdenum (VI) to give 5a and b . This allows for the facile introduction of the C-9a methoxy group into the mitomycin skeleton." @default.
- W2949675865 created "2019-06-27" @default.
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- W2949675865 date "2010-08-04" @default.
- W2949675865 modified "2023-09-26" @default.
- W2949675865 title "ChemInform Abstract: A Total Synthesis of (.+-.)-Mitomycin K. Oxidation of the Mitosene C9- 9a Double Bond by (Hexamethylphosphoramido)oxodiperoxomolybdenum(VI) ( MoO5×HMPA)." @default.
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- W2949675865 doi "https://doi.org/10.1002/chin.199647271" @default.
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