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- W2949677966 abstract "Abstract Black single crystals of nine ternary iodides A II MI 4 (A = Sr, Ba, Nd, Sm, Eu; M = La, Ce) have been obtained from reactions of the metals A with the triiodides of M in sealed tantalum containers at elevated temperatures. They all crystallize isotypically with BaLaI 4 (monoclinic, I2/a, Z = 4). The most important structural feature are chains of face‐sharing square antiprisms [MI 8 ] in accord with the formula A[MI 8/2 ]. M‐M distances are, on the average, 370.6 and 367.9 pm for M = La and Ce, respectively. With all M‐M distances equal, these iodides are expected to be one‐dimensional metals according to the formulation (A 2+ )(M 3+ )(e ‐ )(I ‐ ) 4 with the excess electron residing in a 5d band." @default.
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- W2949677966 date "2004-10-26" @default.
- W2949677966 modified "2023-10-17" @default.
- W2949677966 title "New Ternary Iodides of Lanthanum and Cerium, A<sup>II</sup>MI<sub>4</sub> (A = Sr, Ba, Nd, Sm, Eu; M = La, Ce)" @default.
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- W2949677966 doi "https://doi.org/10.1002/zaac.200400172" @default.
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