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- W2949697831 abstract "Abstract The electrochemistry for the reduction of tetrakis(dialkyl- and diphenyldithiocarbamato)-μ-oxodioxodirhenium complexes trans -Re 2 O 3 (S 2 CNR 2 ) 4 (R = methyl, ethyl, propyl, butyl and phenyl) was investigated in seven nonaqueous solvents. The complexes underwent a reversible reduction involving one- electron at a platinum electrode to [Re 2 O 3 (S 2 CNR 2 ) 4 ] − , which decomposed with the cleavage of the μ-oxo bridge to form ReO(S 2 CNR 2 ) 2 , R 2 CNS 2 − and other rhenium complexes. The redox potential E o ′ of [Re 2 O 3 (S 2 CNR 2 ) 4 ] 0/− couples and the stability of the reduction product [Re 2 O 3 (S 2 CNR 2 ) 4 ] − depend on the R group. The E o ′ are appreciably solvent-dependent. The difference in E o ′ with solvents could be interpreted in terms of the solubility parameters." @default.
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- W2949697831 date "1988-10-04" @default.
- W2949697831 modified "2023-09-26" @default.
- W2949697831 title "ChemInform Abstract: Electrochemical Reduction of Rhenium(V) Dithiocarbamate Complexes trans-Re2O3(S2CNR2)4 in Nonaqueous Media." @default.
- W2949697831 cites W2041202214 @default.
- W2949697831 doi "https://doi.org/10.1002/chin.198840222" @default.
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