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- W2949698052 abstract "We report a new set of reactions based on the Pd-catalyzed alkylation of methylene C(sp3)–H bonds of aliphatic quinolyl carboxamides with α-haloacetate and methyl iodide and applications in the stereoselective synthesis of various β-alkylated α-amino acids. These reactions represent the first generally applicable method for the catalytic alkylation of unconstrained and unactivated methylene C–H bonds with high synthetic relevance. When applied with simple isotope-enriched reagents, they also provide a convenient and powerful means to site-selectively incorporate isotopes into the carbon scaffolds of amino acid compounds." @default.
- W2949698052 created "2019-06-27" @default.
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- W2949698052 date "2013-12-19" @default.
- W2949698052 modified "2023-09-26" @default.
- W2949698052 title "ChemInform Abstract: Stereoselective Synthesis of β-Alkylated α-Amino Acids via Palladium-Catalyzed Alkylation of Unactivated Methylene C(sp3)-H Bonds with Primary Alkyl Halides." @default.
- W2949698052 cites W2333609839 @default.
- W2949698052 doi "https://doi.org/10.1002/chin.201402051" @default.
- W2949698052 hasPublicationYear "2013" @default.
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