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- W2949698493 abstract "Palladium(0)-catalyzed carbocyclization of 1,7-enynes mediated by (chlorodimethylsilyl)pinacolborane proceeds with 1,8-addition of the silicon and boron functions to give functionalized cyclohexane derivatives with boron attached to the exocyclic olefin. A variety of chromane dervatives are accessible by this method. In contrast to the analogous reactions with 1,6-enynes, the configuration of the newly formed stereogenic center is controlled by a stereogenic center present in the substrate." @default.
- W2949698493 created "2019-06-27" @default.
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- W2949698493 date "2016-05-01" @default.
- W2949698493 modified "2023-10-02" @default.
- W2949698493 title "ChemInform Abstract: Silaborative Carbocyclizations of 1,7-Enynes. Diastereoselective Preparation of Chromane Derivatives." @default.
- W2949698493 cites W2223583048 @default.
- W2949698493 doi "https://doi.org/10.1002/chin.201622193" @default.
- W2949698493 hasPublicationYear "2016" @default.
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