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- W2949708506 abstract "A new ordering scheme in cationic-deficient perovskite-like phases of the Ban(Mo,Nb)n-δO3n-x system has been described for the composition Ba3MoNbO8.5, which has an oxygen stoichiometry between those of the 9R polytype and the palmierite structure. An electron diffraction and high-resolution electron microscopy study shows that the oxygen defect with respect to the 9R polytype (hhc)3 leads to an ordered distribution of octahedra and tetrahedra in a 3:2 ratio in the cubic layers. The flexibility of the (hhc)3 stacking sequence allows the formation of a modulated structure through an ordered shearing mechanism along c by introducing mixed BaO2.6 cubic layers in the 9R polytype." @default.
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- W2949708506 date "1998-05-21" @default.
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- W2949708506 title "Electron Microscopy Study of a New Cation Deficient Perovskite-like Oxide: Ba<sub>3</sub>MoNbO<sub>8.5</sub>" @default.
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- W2949708506 doi "https://doi.org/10.1021/cm9708022" @default.
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