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- W2949709217 abstract "The reaction of B10H12(SMe2)2 (1) with HN3 yields arachno-B10H12(N3)(NH2) (2), a product with a μ-NH2 group. Compound 2 can be hydrolysed to give the known arachno-B9H13(NH3) (3). nido-NB9H11(N3) (4) is formed from 2 by a deprotonation/protonation sequence. The azaborane nido-NB10H13 (5) is a product of the thermolysis of 2. The structures of 2–5 are elucidated by 2-D COSY 11B–11B NMR spectra; the structure of 2 is also elucidated by an X-ray structure analysis." @default.
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- W2949709217 date "1990-12-01" @default.
- W2949709217 modified "2023-10-16" @default.
- W2949709217 title "The reaction of decaborane with hydrazoic acid: A novel access to azaboranes" @default.
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- W2949709217 doi "https://doi.org/10.1002/hc.520010606" @default.
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