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• W2949710318 abstract "Magnesium borohydride, Mg(BH4)2, a long-sought candidate for efficient hydrogen storage chemisorption technology, has been obtained in a pure and crystalline form by two new synthetic routes in a hydrocarbon solvent. A first synthetic approach involves a metathetical reaction between organometallic magnesium compounds; a second route consists of an insertion reaction of BH3 species, released from BH3·S(CH3)2, into the Mg−C bonds of MgR2, with complete replacement of R groups with BH4 groups. Both methods, based on commercially available reagents, afford identical, pure, polycrystalline materials, identified by X-ray diffraction as the so-called low-temperature hexagonal form of Mg(BH4)2, stable below 180 °C, recently shown to possess a complex, unpredictable, crystal structure." @default.
• W2949710318 created "2019-06-27" @default.
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• W2949710318 date "2007-09-28" @default.
• W2949710318 modified "2023-10-16" @default.
• W2949710318 title "Facile High-Yield Synthesis of Pure, Crystalline Mg(BH₄)₂" @default.
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• W2949710318 doi "https://doi.org/10.1021/ic701436c" @default.
• W2949710318 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17900187" @default.
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