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- W2949720171 abstract "A short and efficient synthesis, solvent extraction and potentiometric measurements of new thiazole-containing naphtho-crown ethers are reported. The naphthalene moiety enhances the ammonium ion selectivity over potassium ion. The selectivity of <TEX>${NH_4}^+/K^+$</TEX> follows the trend <TEX>$3;{approx};2;>;1$</TEX>, indicating that the differences in conformational changes of 2 and 3 in forming ammonium complexes affect little on the resulting ammonium/potassium extraction selectivity ratio. The ammonium ion-selective electrodes were prepared with noctylphenyl ether plasticized poly(vinyl chloride) membranes containing 1-4 the effect of one naphthalene unit introduced on either right (2) or left (3) side of thiazolo-crown ether on their potentiometric properties (e.g., ammonium ion selectivity over other cations, response slopes, and detection limits) were not apparent. However, the ammonium ion selectivity of 1, 2 and 3 over other alkali metal and alkaline earth metal cations is 10-100 times higher than that of nonactin." @default.
- W2949720171 created "2019-06-27" @default.
- W2949720171 date "2004-10-20" @default.
- W2949720171 modified "2023-09-25" @default.
- W2949720171 title "Ammonium Ion Binding Property of Naphtho-Crown Ethers Containing Thiazole as Sub-Cyclic Unit" @default.
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- W2949720171 doi "https://doi.org/10.5012/bkcs.2004.25.10.1465" @default.
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