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- W2949726173 abstract "A practical synthesis of ( rac)-muscone in three steps is described, using commercially available 1,10-dibromodecane as the starting material. In the first step, an aldol reaction of 1,10-dibromodecane with ethyl acetoacetate affords the important intermediate 2,15-hexadecanedione in 70% yield. A cyclisation reaction in the second step aided by propyl zinc iodide gives dehydro-muscone in 84% yield. Hydrogenation of dehydro-muscone with Pd–-C completes the synthesis of ( rac)-muscone. Furthermore, ( R)-(–-)-muscone is enantioselectively prepared via the formation of a ketal intermediate from dehydro-muscone and 1,4-di- O-benzyl- D-threitol." @default.
- W2949726173 created "2019-06-27" @default.
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- W2949726173 date "2011-04-01" @default.
- W2949726173 modified "2023-09-26" @default.
- W2949726173 title "A Practical Synthesis of (rac)-Muscone and (R)-(–-)-muscone" @default.
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- W2949726173 doi "https://doi.org/10.3184/174751911x12992369451085" @default.
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