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- W2949739380 abstract "Platinum-catalyzed asymmetric hydrophosphination of activated olefins using the catalyst precursor Pt(R,R-Me-Duphos)(trans-stilbene) (1) gives chiral phosphines with control of stereochemistry at phosphorus or carbon centers. Stoichiometric reactions of 1 allow observation of P−H oxidative addition, diastereoselective olefin insertion, and reductive elimination steps, which make up the proposed catalytic cycle." @default.
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- W2949739380 date "2000-02-24" @default.
- W2949739380 modified "2023-10-14" @default.
- W2949739380 title "Pt(Me-Duphos)-Catalyzed Asymmetric Hydrophosphination of Activated Olefins: Enantioselective Synthesis of Chiral Phosphines" @default.
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- W2949739380 doi "https://doi.org/10.1021/om990882e" @default.
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