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- W2949740539 abstract "Abstract We have reported the Grignard reaction of Halothane, 2-bromo-2-chloro-1,1,1-trifluoroethane (1), with ketones gave unexpected products, α-(1-bromo-1-chloro-2,2,2-trifluoroethyl)alcohols (4) at a low temperature. However, this reaction hardly proceeded with aldehydes. Now, we found the reaction of 1 with aldehydes in the presence of zinc gave not only products of type 4, but α-(1-chloro-2,2,2-trifluoroethyl)alcohols (3), the expected type of products, under mild conditions in good to moderate yields." @default.
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- W2949740539 date "1996-09-01" @default.
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- W2949740539 title "Synthesis of fluorine compounds using zinc complex of halothane" @default.
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- W2949740539 doi "https://doi.org/10.1016/0040-4020(96)00722-3" @default.
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