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- W2949742017 abstract "The combination of aryl bromides, allylbenzene, base and a palladium catalyst usually results in a Heck reaction. Herein we combine these same reagents, but override the Heck pathway by employing a strong base. In the presence of LiN(SiMe3)2, allylbenzene derivatives undergo reversible deprotonation. Transmetalation of the resulting allyllithium intermediate to LPdAr(Br) and reductive elimination provide the 1,1-diarylprop-2-enes, which are not accessible by the Heck reaction. The regioselectivity in this deprotonative cross-coupling process is catalyst-controlled and very high." @default.
- W2949742017 created "2019-06-27" @default.
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- W2949742017 date "2014-08-21" @default.
- W2949742017 modified "2023-09-27" @default.
- W2949742017 title "ChemInform Abstract: Chemo- and Regioselective C(sp3)-H Arylation of Unactivated Allylarenes by Deprotonative Cross-Coupling." @default.
- W2949742017 cites W1966742820 @default.
- W2949742017 doi "https://doi.org/10.1002/chin.201436102" @default.
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