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- W2949752765 abstract "Four distinct sets of functionalized quinolines were synthesized by reacting 2‐chloroquinoline‐3‐carbonitriles with various types of isocyanides under appropriate conditions. The palladium‐catalysed reaction of less hindered aliphatic and aromatic isocyanides with 2‐chloroquinoline‐3‐carbonitriles yielded 2‐alkyl(aryl)‐1‐imino‐1 H ‐pyrrolo[3,4‐ b ]quinolin‐3(2 H )‐one derivatives; however, the catalysed reaction of more hindered isocyanides such as tert ‐butyl isocyanide produced the corresponding 3‐cyanoquinoline‐2‐carboxamides. Interestingly, chloroquinoline‐3‐carbonitriles reacted with ethyl isocyanoacetate in the presence of Cs 2 CO 3 to generate imidazo[1,5‐ a ]quinoline derivatives; notably, tosylmethyl isocyanide under the same conditions formed unprecedented 2‐tosyl‐3‐cyanoquinolines." @default.
- W2949752765 created "2019-06-27" @default.
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- W2949752765 date "2019-06-10" @default.
- W2949752765 modified "2023-10-17" @default.
- W2949752765 title "Synthesis of four series of quinoline‐based heterocycles by reacting 2‐chloroquinoline‐3‐carbonitriles with various types of isocyanides" @default.
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- W2949752765 doi "https://doi.org/10.1002/aoc.5024" @default.
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