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- W2949766098 abstract "The titled compound (3) was prepared by treating commercially available 3-(trifluoromethyl)phenothiazine successively with sodium hydride, methyl iodide, and N-bromosuccinimide, and its structure was ascertained by X-ray analysis. The reaction of 3 with certain aliphatic nitriles and LDA gave typical 7- and 6-addition products via aryne (4) in ratios of ca. 85:15, 5:6, respectively. However, treatment of 3 with certain primary and secondary amines and the corresponding lithiated amide afforded a single 7-aminated product (7) in good yields in each case" @default.
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- W2949766098 date "1990-01-01" @default.
- W2949766098 modified "2023-09-27" @default.
- W2949766098 title "Synthesis and Reaction of 7-Bromo-2-(trifluoromethyl)-10-methylphenothiazine with Nitriles and Amines under Aryne-forming Conditions" @default.
- W2949766098 doi "https://doi.org/10.3987/com-90-5591" @default.
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