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- W2949781063 abstract "Two methods for the synthesis of benzyl esters from carboxylic acids using the O-benzylating reagent 2,4,6-tris(benzyloxy)-1,3,5-triazine (TriBOT) have been developed. The reactions were conducted either in the presence of a catalytic amount of TfOH at room temperature (acidic conditions) or in the absence of TfOH at 180–230 °C (thermal conditions). Interestingly, the O-benzylation of hydroxy carboxylic acids under the two conditions afforded different products: The dibenzylated product under acidic conditions and the hydroxy ester under thermal conditions. In addition to these results, other evidence indicated that the former reaction proceeds through an SN1-type mechanism, and the latter by an SN2-type mechanism." @default.
- W2949781063 created "2019-06-27" @default.
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- W2949781063 date "2016-03-01" @default.
- W2949781063 modified "2023-09-27" @default.
- W2949781063 title "ChemInform Abstract: O-Benzylation of Carboxylic Acids Using 2,4,6-Tris(benzyloxy)-1,3,5-triazine (TriBOT) under Acidic or Thermal Conditions." @default.
- W2949781063 cites W2219656349 @default.
- W2949781063 doi "https://doi.org/10.1002/chin.201616077" @default.
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