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- W2949791001 abstract "A Rh(III)-catalyzed selective C–H amination of 2-phenylpyridine derivatives is reported. With pyridine as a directing group, the reaction has high mono- or diamination selectivity, and a wide range of effective substrates, including electron-deficient and -rich aryl azides. Water helps to promote C–H activation, and the concept of a water promoted rollover mechanism is postulated for the diamination step. The reactions were conducted using a Schlenk flask and proceeded smoothly “on water” under atmospheric conditions with nitrogen gas as the only byproduct." @default.
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- W2949791001 date "2016-07-01" @default.
- W2949791001 modified "2023-09-23" @default.
- W2949791001 title "ChemInform Abstract: Rhodium-Catalyzed Selective Mono- and Diamination of Arenes with Single Directing Site “On Water”." @default.
- W2949791001 cites W2294245738 @default.
- W2949791001 doi "https://doi.org/10.1002/chin.201630084" @default.
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