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- W2949803021 abstract "The new N-Fmoc 3-iodoalanine tert-butyl ester derived organozinc reagent 1, obtained in 7 steps from optically pure L-serine, was coupled to a range of electrophiles under palladium catalysis to give substituted phenylalanines and 4-oxoamino acids in variable yields (21–59%). Transformation into the organocopper reagent 13 allowed coupling with allyl chloride and ethyl oxalyl chloride. Removal of the tert-butyl group gives Fmoc-protected amino acids (63–95%), suitable for use in automated solid phase peptide synthesis." @default.
- W2949803021 created "2019-06-27" @default.
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- W2949803021 date "2010-05-23" @default.
- W2949803021 modified "2023-09-26" @default.
- W2949803021 title "ChemInform Abstract: Direct Synthesis of Fmoc-Protected Amino Acids Using Organozinc Chemistry: Application to Polymethoxylated Phenylalanines and 4-Oxoamino Acids." @default.
- W2949803021 cites W2138305638 @default.
- W2949803021 doi "https://doi.org/10.1002/chin.200151189" @default.
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