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- W2949811962 abstract "The hydrogenation of the double bond of styrene-Cr(CO)3 and some dihydronaphthalene-Cr(CO)3 derivatives is achieved using samarium(II)iodide in the presence of water. 1,2-Dihydronaphthalene complexes carrying olefinic side chains in 4-position are reduced with virtually complete regio- and diastereocontrol leading to 1-endo-substituted tetralin complexes. The reactions seem to proceed via Cr(CO)3 complexed benzylic radicals which are trapped by electron transfer to give the corresponding Cr-stabilized benzylic anions." @default.
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- W2949811962 date "1998-09-01" @default.
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- W2949811962 title "Electron transfer driven reactions of transition metal π-complexes: Hydrogenation of styrene-Cr(CO)3 derivatives by samarium(II)iodide in the presence of water" @default.
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- W2949811962 doi "https://doi.org/10.1016/s0040-4039(98)01436-1" @default.
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