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- W2949839858 abstract "Abstract The reaction of allylic or benzylic alcohols 1 with n-butyllithium followed by treatment with lithium powder and a catalytic amount of DTBB (5 mol %) in THF at room temperature gives a solution of the corresponding alkyllithium reagent, which reacts in situ with different electrophiles to yield the expected products 2. Alternatively, the O-silylated derivatives of the same alcohols are lithiated under Barbier-type reaction conditions to afford the same reaction products with better yields." @default.
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- W2949839858 date "2010-08-12" @default.
- W2949839858 modified "2023-09-24" @default.
- W2949839858 title "ChemInform Abstract: Direct Transformation of Allylic and Benzylic Alcohols or Their Silylated Derivatives into Organolithium Compounds." @default.
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- W2949839858 doi "https://doi.org/10.1002/chin.199608192" @default.
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