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- W2949841796 abstract "Facile and effective access for the asymmetric construction of the useful and important skeleton of the bicyclic N,O-acetals is described. CuII/SaBOX could catalyze the reaction of β,γ-unsaturated α-ketoesters with cyclic enamines efficiently, thus affording the desired products in excellent yields with excellent stereoselectivities (21 examples; up to 99 % yields; up to >95:5 d.r.; and 95–99 % ee). This reaction can be well performed on gram scale, even with only 1 mol % catalyst loading. The single-crystal structures of the copper complexes lead to a good understanding of the stereo-synergistic effects of the sidearm." @default.
- W2949841796 created "2019-06-27" @default.
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- W2949841796 date "2016-09-01" @default.
- W2949841796 modified "2023-09-26" @default.
- W2949841796 title "ChemInform Abstract: Cy-SaBOX/Copper(II)-Catalyzed Highly Diastereo- and Enantioselective Synthesis of Bicyclic N,O Acetals." @default.
- W2949841796 cites W2468420051 @default.
- W2949841796 doi "https://doi.org/10.1002/chin.201642171" @default.
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