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- W2949842854 abstract "The Michael addition to α-substituted α,β-unsaturated esters and amides using complex A containing a chiral odorless thiol proceeded diastereoselectively. The Michael adducts were converted to β-mercapto esters and amides via a Wagner−Meerwein rearrangement with boron trifluoride etherate and a thiol exchange reaction using odorless 1-dodecanethiol. This conversion constitutes a formal asymmetric Michael addition of hydrogen sulfide to α,β-unsaturated carbonyl compounds using odorless thiols instead of the toxic hydrogen sulfide." @default.
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- W2949842854 date "2001-08-31" @default.
- W2949842854 modified "2023-10-16" @default.
- W2949842854 title "Use of Odorless Thiols: Formal Asymmetric Michael Addition of Hydrogen Sulfide to α-Substituted α,β-Unsaturated Carbonyl Compounds" @default.
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- W2949842854 doi "https://doi.org/10.1021/ol016406d" @default.
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