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- W2949844582 abstract "Ruthenium tetroxide oxidation of N, C-protected derivatives of L-2, 4-diaminobutyric acid, L-ornithine and L-lysine was carried out under two-phase conditions and the corresponding imides, formed through the oxidation of the methylene adjacent to the ω-amino group, were obtained in good yields. Removal of the protecting groups from the products gave L-asparagine, L-glutamine and L-2-aminoadipic acid 6-amide, respectively. Thus, the first chemical conversion of L-α, ω-diamino acids into the corresponding L-ω-carbamoyl-α-amino acids without racemization has been established. L-2-Aminoadipic acid 6-amide was further converted to L-2-aminoadipic acid by acid hydrolysis. This represents a convenient method for the synthesis of L-2-aminoadipic acid starting from L-lysine." @default.
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- W2949844582 date "1988-01-19" @default.
- W2949844582 modified "2023-09-23" @default.
- W2949844582 title "ChemInform Abstract: Chemical Conversion of L-α,ω-Diamino Acids to L-ω-Carbamoyl-α-amino Acids by Ruthenium Tetroxide Oxidation." @default.
- W2949844582 cites W2007879143 @default.
- W2949844582 doi "https://doi.org/10.1002/chin.198803316" @default.
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