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- W2949846992 abstract "The rates of base-catalyzed hydrolysis of pseudo esters derived from y-keto acids show strikingly poor sensitivity to the nature of the leaving group.la The rates vary in the narrow range of about 12-fold as contrasted to a 103-fold spread of the corresponding benzoate esters. The results presented are consistent with a rate-determining formation of a tetrahedral intermediate (11) and i t s rapid collapse, by the cleavage of the lactone ring in a fast step." @default.
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- W2949846992 date "1977-12-06" @default.
- W2949846992 modified "2023-09-24" @default.
- W2949846992 title "ChemInform Abstract: ASPECTS OF TAUTOMERISM. 6. BASE-CATALYZED HYDROLYSIS OF PSEUDO ESTERS OF Γ-KETO ACIDS" @default.
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- W2949846992 doi "https://doi.org/10.1002/chin.197749221" @default.
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