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• W2949858314 abstract "The first structurally characterized iridium-substituted polyoxometalate, K14[(IrCl4)KP2W20O72]·23H2O [1; orthorhombic Pnnm, with a = 18.6546(7) Å, b = 19.5192(6) Å, c = 14.8670(5) Å, V = 5413.4(3) Å3, and Z = 2, final R = 0.0730], is reported. Elemental analysis, X-ray crystallography, and NMR all indicate one Ir atom in each molecule, while IR and electronic absorption spectroscopy, thermal gravimetric analysis, and electrochemistry all indicate its purity in both solid and solution states. Complex 1 is a molecular model of iridium supported on redox-active metal oxides, and aqueous solutions of 1 catalyze oxidation of water to O2." @default.
• W2949858314 created "2019-06-27" @default.
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• W2949858314 date "2009-05-26" @default.
• W2949858314 modified "2023-10-09" @default.
• W2949858314 title "Structurally Characterized Iridium(III)-Containing Polytungstate and Catalytic Water Oxidation Activity" @default.
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• W2949858314 doi "https://doi.org/10.1021/ic900538g" @default.
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