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• W2949869004 abstract "A series of homologous α-sulfonamidyl radicals has been generated by reaction of α-halomethyl precursors with tri-n-butyltin hydride under AIBN catalysis. The intramolecular cyclization capability of these highly reactive intermediates has been evaluated. Where possible, five-membered sultams are formed by 5-exo transition states. The longer C−SO2 and SO2−NR2 bonds have little demonstrable effect on this pathway. In larger systems, however, the 7-endo option predominates over the 6-exo alternative. A preparatively useful route to sultams has emerged from this investigation." @default.
• W2949869004 created "2019-06-27" @default.
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• W2949869004 date "1999-11-23" @default.
• W2949869004 modified "2023-09-24" @default.
• W2949869004 title "Intramolecular Cyclization of Radicals Generated from α-Halomethylsulfonamides" @default.
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• W2949869004 doi "https://doi.org/10.1021/jo991344e" @default.
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