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- W2949898286 abstract "A chiral iridium(I) N-heterocyclic carbene complex was reported for the first time as the catalyst in the highly enantioselective intramolecular allylic amination reaction. The current method provides facile access to biologically important enantioenriched indolopiperazinones and piperazinones in good yields (74-91 %) and excellent enantioselectivities (92-99 % ee). Preliminary mechanistic investigations reveal that the C-H activation occurs at the position ortho to the N-aryl group of the ligand." @default.
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- W2949898286 date "2016-11-01" @default.
- W2949898286 modified "2023-09-26" @default.
- W2949898286 title "ChemInform Abstract: An Iridium(I) N-Heterocyclic Carbene Complex Catalyzes Asymmetric Intramolecular Allylic Amination Reactions." @default.
- W2949898286 cites W2369296454 @default.
- W2949898286 doi "https://doi.org/10.1002/chin.201647190" @default.
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