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- W2949903112 abstract "1,2-addition of organolithium and organomagnesium derivatives to β-substituted (N-Boc)-β-aminoaldehydes gave access to enantiomerically pure, 1,3-disubstituted, 1,3-aminoalcohols. A diastereoselective version of this addition was also investigated and Gilman cuprates were found to add onto aldehydes 1a–b with notable diastereoselectivity (up to 70% de) in favour of the anti isomer. The absolute configuration of each obtained 1,3-aminoalcohol was determined." @default.
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- W2949903112 date "2000-04-01" @default.
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- W2949903112 title "Organometallic Additions to β-substituted N-Boc-β-aminoaldehydes: a New Synthesis of Enantiomerically Pure 1,3-disubstituted N-Boc-1,3-aminoalcohols" @default.
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- W2949903112 doi "https://doi.org/10.1016/s0040-4020(00)00155-1" @default.
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