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- W2949905489 abstract "Abstract Standard enthalpies of formation in the crystalline and gaseous states have been determined for acetylurea and trimethyl isocyanurate by oxygen bomb-combustion calorimetry and sublimation calorimetry. Derived values are as follows: −Δ f H m o (c) −Δ f H m o (g) (kJ·mol−1) (kJ·mol−1) CH3CONHCONH2 544.21 ± 0.54 441.16 ± 0.86 CON(CH3)CON(CH3)CON(CH3) 677.92 ± 0.97 589.7 ± 1.5 Stabilization energies related to intramolecular interaction between π-electrons of carbonyl groups and lone-pair electrons of adjacent nitrogen atoms have been evaluated for acetamide and urea as well as for these compounds as enthalpy changes of “isodesmic” reactions using ethane as a reagent for the cleavage of CON bonds and are discussed." @default.
- W2949905489 created "2019-06-27" @default.
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- W2949905489 date "1988-06-28" @default.
- W2949905489 modified "2023-09-26" @default.
- W2949905489 title "ChemInform Abstract: Combustion and Sublimation Calorimetric Studies on Acetylurea and Trimethyl Isocyanurate" @default.
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- W2949905489 doi "https://doi.org/10.1002/chin.198826079" @default.
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