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- W2949929172 abstract "Nitrosation of 3-alkyl-1-arylureas was investigated with sodium nitrite in 99% formic acid or with isoamyl nitrite in chloroform. The preparation of 3-alkyl-1-aryl-1-nitrosoureas was effectively performed by using isoamyl nitrite in the absence of acids, since the 1-nitrosoureas were isomerized to the 3-nitroso isomers by acids. The carbon-13 nuclear magnetic resonance and infrared spectral properties of the products were examined and their structural features are discussed.It was found that 3-alkyl-1-aryl-1-nitrosoureas decomposed to form alkyl isocyanates and 3-alkyl-1- (2-nitroaryl) ureas in carbon tetrachloride. 1, 3-Rearrangement and transnitrosation also took place in this solvent." @default.
- W2949929172 created "2019-06-27" @default.
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- W2949929172 date "1987-10-27" @default.
- W2949929172 modified "2023-09-26" @default.
- W2949929172 title "ChemInform Abstract: Preparation and Properties of 3-Alkyl-1-arylnitrosoureas and Related Compounds." @default.
- W2949929172 cites W2059708871 @default.
- W2949929172 doi "https://doi.org/10.1002/chin.198743155" @default.
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