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- W2949966500 abstract "Novel, enantiomerically pure organoantimony compounds having a C-chiral amine moiety, (S)-(alpha-methyl-2-di-p-tolylstibanobenzyl)dimethylamine [AMSb] (2) and its (eta(6)-arene)chromium complex [AMSb-Cr(CO)(3)] (4), were prepared from common (S)-(alpha-methylbenzyl)dimethylamine (1) via its ortho-lithiated intermediates in short steps. The catalytic activity and enantioselectivity of the ligands 2 and 4 for asymmetric reaction are evaluated, and the optically active (eta(6)-arene)chromium complex 4 has been shown to be an effective ligand for rhodium-catalyzed asymmetric hydrosilylation of ketones." @default.
- W2949966500 created "2019-06-27" @default.
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- W2949966500 date "2003-04-08" @default.
- W2949966500 modified "2023-09-27" @default.
- W2949966500 title "Synthesis of Optically Active Organoantimony Compounds Having an (S)-α-Methylbenzyldimethylamine Group and Its Evaluation for Asymmetric Reaction." @default.
- W2949966500 cites W2142125692 @default.
- W2949966500 doi "https://doi.org/10.1002/chin.200314033" @default.
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