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- W2949972896 abstract "By adjustment of the electronic properties of the ancilliary ligands, high selectivity can be achieved for either [4 + 2] or [4 + 3] cycloaddition reactions of allene-dienes catalyzed by gold(I). Triarylphosphitegold(I) complexes are employed as catalysts for a [4 + 2] cycloaddition reaction leading to alkylidenecyclohexenes. Conversely, di-tert-butylbiphenylphosphinegold(I)-catalyzed reactions afford cycloheptadienes via [4 + 3] cycloaddition reactions." @default.
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- W2949972896 date "2009-09-22" @default.
- W2949972896 modified "2023-09-24" @default.
- W2949972896 title "ChemInform Abstract: Ligand-Controlled Access to [4 + 2] and [4 + 3] Cycloadditions in Gold-Catalyzed Reactions of Allene-Dienes." @default.
- W2949972896 cites W2074062344 @default.
- W2949972896 doi "https://doi.org/10.1002/chin.200938094" @default.
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