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- W2949975810 abstract "Abstract At 130°C and in the presence of compressed CO 2 , primary aliphatic amines [RNH 2 , R=C 10 H 21 , C 8 H 17 , cHex, 1-(C 10 H 7 )CH 2 ] react with organic carbonates (R′OCO 2 R; R′=Me, Et) to give alkyl carbamates (RNHCO 2 R′, 1 ). Although CO 2 promotes the reaction also at a low pressure, good yields (∼80%) of 1 are achievable only with supercritical carbon dioxide (scCO 2 ) at 90 bar, which inhibits the formation of N -methylated by-products." @default.
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- W2949975810 date "2010-05-21" @default.
- W2949975810 modified "2023-09-26" @default.
- W2949975810 title "ChemInform Abstract: The Synthesis of Alkyl Carbamates from Primary Aliphatic Amines and Dialkyl Carbonates in Supercritical Carbon Dioxide." @default.
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- W2949975810 doi "https://doi.org/10.1002/chin.200222067" @default.
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