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- W2949978801 abstract "3, 5-Dimethyl-4-iodoisoxazole (1a) reacted with phenylacetylene with catalysis by palladium (II) chloride-triphenylphosphine complex to give 3, 5-dimethyl-4-phenylethynyl-isoxazole (2a). When 1a was treated with styrene under similar conditions, 3, 5-dimethyl-4-trans-styrylisoxazole (3a) was obtained. In contrast, the palladium-catalyzed crosscoupling reaction of 3-phenyl-5-bromoisoxazole (4) with styrene afforded 3, 3'-diphenyl-5, 5'-biisoxazole (6) as the main product, instead of the desired styryl compound (5a). However, 3-phenyl-5-phenylethynylisoxazole (7a) was obtained, as in the case of 1a, by the reaction of 4 with phenylacetylene. Some additional examples of these coupling reactions are also described." @default.
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- W2949978801 date "1982-06-15" @default.
- W2949978801 modified "2023-09-25" @default.
- W2949978801 title "ChemInform Abstract: CROSS-COUPLING REACTIONS OF HALOISOXAZOLES WITH OLEFINS AND ACETYLENES" @default.
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- W2949978801 doi "https://doi.org/10.1002/chin.198224211" @default.
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