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- W2949996585 abstract "This article presents our work on the σ-Ferrier ring-expansion of carbohydrate derived vinylcyclopropanes (VCPs) under electrophilic conditions mediated by chloramine-T and a phase-transfer catalyst. The present work serves as the first example on the studies of the reactivity of carbohydrate VCPs towards the synthesis of densely functionalized oxepane analogues. The work elaborates on a reasonable mechanism for the product formation and our observations on the diastereoselectivity based on control experiments and gas-phase calculations." @default.
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- W2949996585 date "2014-10-01" @default.
- W2949996585 modified "2023-10-16" @default.
- W2949996585 title "σ-Ferrier rearrangement of carbohydrate derived vinylcyclopropanes: a facile approach to oxepane analogs" @default.
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- W2949996585 doi "https://doi.org/10.1016/j.tet.2014.07.004" @default.
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