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- W2950006556 abstract "Abstract The syn ‐selective direct aldol reaction of unprotected dihydroxyacetone with glyceraldehyde has been catalyzed by serine‐based organocatalysts. The application of the catalysts mimics the biosynthesis of ketohexoses in aqueous solvents and leads to fructose and sorbose with excellent diastereoselectivity (up to 95:5 dr ). The organocatalytic C 3 + C 3 methodology presented herein is a versatile direct entry to protected syn ‐configured sugars of both the D and L series." @default.
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- W2950006556 date "2013-10-16" @default.
- W2950006556 modified "2023-10-12" @default.
- W2950006556 title "Biomimetic<i>syn</i>-Aldol Reaction of Dihydroxyacetone Promoted by Water-Compatible Catalysts" @default.
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- W2950006556 doi "https://doi.org/10.1002/ejoc.201301436" @default.
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