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- W2950022010 abstract "2,3-Dihydro-2,2,9-trimethyl-1 H -pyrrolo[1,2- a ]indol-1-amine and its 1-(1-pyrrolidinyl) analog have been synthesized from the corresponding 1-ol via mesylation in pyridine followed by treatment with pyrrolidine. Mechanisms of the former, unexpected amination are briefly discussed. Evidence is presented that the pyridine ring serves as a masked amino group. The phenomenon is partly attributed to steric congestion. Similar preparation of 2-bromo-6,7,8,9-tetrahydro-8,8,10-trimethylpyridol[1,2- a ]indol-9-amine supports this notion." @default.
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- W2950022010 date "1991-01-01" @default.
- W2950022010 modified "2023-09-25" @default.
- W2950022010 title "Unusual formation of sterically hindered primary amines in a series of pyrrolo- and pyrido[1,2-a]indoles" @default.
- W2950022010 doi "https://doi.org/10.1135/cccc19912278" @default.
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