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- W2950038426 abstract "Studies in the Rb–Eu–In–Ge system confirm the existence of the phase Rb 8− x Eu x (In,Ge) 46 (0.6 ≤ x ≤ 1.8), crystallizing with the cubic clathrate type-I structure. The In and Ge content can be varied, concomitant with changes in the Rb–Eu ratio. Two of the three framework sites are occupied by statistical mixtures of Ge and In atoms, while the site with the lowest multiplicity is taken by the In atoms only. Based on the three refined formulae [heptarubidium europium nonaindium heptatriacontagermanide, Rb 7.39(3) Eu 0.61(3) In 8.88(5) Ge 37.12(5) , and two forms of hexarubidium dieuropium decaindium hexatriacontagermanide, Rb 6.30(3) Eu 1.70(3) In 9.76(4) Ge 36.24(4) and Rb 6.24(2) Eu 1.76(2) In 10.16(5) Ge 35.84(5) ] and the explored different synthetic routes, it can be suggested that the known ternary phase Rb 8 In 8 Ge 38 and the hypothetical quaternary phase Rb 6 Eu 2 In 10 Ge 36 represent the boundaries of the homogeneity range. In the former limiting composition, both the (Ge,In) 20 and the (Ge,In) 24 cages are fully occupied by Rb atoms only, whereas Rb 6 Eu 2 In 10 Ge 36 has Rb atoms encapsulated in the larger tetrakaidecahedra, with Eu atoms filling the smaller pentagonal dodecahedra. For the solid solutions Rb 8− x Eu x (In,Ge) 46 , Rb and Eu are statistically disordered in the dodecahedral cage, and the tetrakaidecahedral cage is only occupied by Rb atoms." @default.
- W2950038426 created "2019-06-27" @default.
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- W2950038426 date "2013-11-13" @default.
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- W2950038426 title "On the possibility for Rb- and Eu-cation ordering in type-I clathrates: synthesis and homogeneity range of the novel compounds Rb<sub>8–<i>x</i></sub>Eu<sub><i>x</i></sub>(In,Ge)<sub>46</sub>(0.6 ≤<i>x</i>≤ 1.8)" @default.
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- W2950038426 doi "https://doi.org/10.1107/s0108270113030011" @default.
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