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- W2950049836 abstract "A novel, effective 1-glycyl-3-methyl imidazolium chloride–palladium(II) complex ([Gmim]Cl–Pd(II)) was synthesized and studied as an organocatalyst for the Sonogashira coupling reaction under solvent-free conditions at 25 °C. The hydrophobic group on amino acid favors reagent diffusion toward the chloroglycine moiety, increasing the catalytic activity of supported palladium complex. By this protocol, different aryl halides (Cl, Br and I) were reacted with phenylacetylene in good to excellent yields with turnover number 8.0 × 102 to 9.6 × 102. The catalyst was recycled for the reaction of bromobenzene with phenylacetylene for eight runs without appreciable loss of its catalytic activity and negligible metal leaching. Copyright © 2012 John Wiley & Sons, Ltd." @default.
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- W2950049836 date "2012-09-12" @default.
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- W2950049836 title "A novel imidazolium-supported palladium-chloroglycine complex: copper- and solvent-free high-turnover catalysts for the Sonogashira coupling reaction" @default.
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- W2950049836 doi "https://doi.org/10.1002/aoc.2896" @default.
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