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- W2950051007 abstract "Two new 9,13-diepoxy labdane diterpenes, amoenolide K [1] and its 19-acetate [2], were isolated from the aerial parts of the composite Amphiachyris amoena and their structures were established by spectral methods, especially high-field nmr spectroscopy. Amoenolide K [1] was prepared from amoenolide A [3] by singlet oxygen addition via the ene reaction. A study was made of the ene reaction products with amoenolide K triacetate [5] which showed them to arise from stereospecific oxygen addition to the 8,9-double bond, with the exception of the sterically hindered beta-side at C-9, for which no products were isolated." @default.
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- W2950051007 date "1995-09-01" @default.
- W2950051007 modified "2023-09-25" @default.
- W2950051007 title "Amoenolide K and Amoenolide K 19-Acetate, Two Grindelane Peroxides from Amphiachyris amoena. Isolation, Structure Determination, and Preparation of Amoenolide K from Amoenolide A by Photochemical Oxygenation" @default.
- W2950051007 doi "https://doi.org/10.1021/np50123a011" @default.
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