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- W2950065324 abstract "Abstract The relative enthalpies H rel ( T ) = H ( T ) – H (298 K) of K 3 ZrF 7 have been measured by the drop calorimetry in the temperature interval 868–1293 K. The heat capacities have been determined differentiating the temperature dependencies of the relative enthalpies: C p (K 3 ZrF 7 , cr) = (333 ± 10) J mol −1 K −1 and C p (K 3 ZrF 7 , melt) = (358 ± 21) J mol −1 K −1 for the crystalline phase and for the K 3 ZrF 7 melt, respectively. The temperature of fusion determined by calorimetric experiments was 1198 K. The enthalpy and entropy of fusion Δ fus H (K 3 ZrF 7 , 1198 K) = (72 ± 2) kJ mol −1 and Δ fus S (K 3 ZrF 7 , 1198 K) = (60 ± 1.6) J mol −1 K −1 have been determined from the experimental data." @default.
- W2950065324 created "2019-06-27" @default.
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- W2950065324 date "2019-09-01" @default.
- W2950065324 modified "2023-09-24" @default.
- W2950065324 title "Calorimetric investigation of tripotassium zirconate heptafluoride K3ZrF7" @default.
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- W2950065324 doi "https://doi.org/10.1016/j.molliq.2019.111191" @default.
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