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- W2950098654 abstract "An efficient method for the synthesis of 6,11-dihydro[2]benzoxepino[4,3-b]pyridine derivatives via Pd(0) catalyzed intramolecular reductive Heck cyclization is reported. The method offers the regioselective and stereoselective synthesis of highly functionalized pyridine-fused benzoxepine derivatives in 75–85% yields under mild conditions. Chemoselective Sonogashira coupling is utilized for the synthesis of cyclization precursors. The stereochemistry of the exocyclic double bond of 6,11-dihydro[2]benzoxepino[4,3-b]pyridine derivatives is confirmed from single crystal X-ray diffraction. The absence of N–Pd(II) interaction results in a reverse stereochemistry of the exocyclic double bond of dibenzoxepine derivative." @default.
- W2950098654 created "2019-06-27" @default.
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- W2950098654 date "2016-05-01" @default.
- W2950098654 modified "2023-09-27" @default.
- W2950098654 title "ChemInform Abstract: Regioselective and Stereoselective Synthesis of Pyridine-Fused Benzoxepine Derivatives by Intramolecular Reductive Heck Cyclization." @default.
- W2950098654 cites W2301010752 @default.
- W2950098654 doi "https://doi.org/10.1002/chin.201623196" @default.
- W2950098654 hasPublicationYear "2016" @default.
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