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- W2950102006 abstract "1,3-Diphenyl-2-(hydroxyimino)-1,3-propanedione 1 reacted with phosphonium ylides 2a,b to give mainly the substituted 1-hydroxy-2,3-dihydropyrroles 6a,b along with the novel ylides 10a,b whereas the phosphono substituted-N-heterocycles 11a,b and 14a,b were obtained from the reaction of 1 with α-phosphoryl carbanion counterparts 3a,b. Reaction of 1 with cyanomethylene(triphenyl)phosphorane 2c afforded the Wittig product 17 and the oxazole derivative 18 while the phosphono 2,2-disubstituted dihydrooxazole 20 and the diolefin 19 were produced in the reaction with the phosphonate ylide 3c. Application of the unsaturated carbanions 2d and 3d on 1 yielded the pyrrole 23 and the phosphono substituted 2H-1,4-oxazine 25, respectively." @default.
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- W2950102006 date "2002-01-01" @default.
- W2950102006 modified "2023-10-12" @default.
- W2950102006 title "A Comparison of Phosphonium and Phosphonate Carbanion Reagents inReactions with 1,3-Diphenyl-2-(hydroxyimino)-1,3-propanedione" @default.
- W2950102006 doi "https://doi.org/10.1055/s-2002-33526" @default.
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