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- W2950106438 abstract "Abstract A simple methodology is developed to realize chiroptical function induced through superstructural chirality of a matrix of helical nanofilaments formed by achiral molecules. In this work, circularly polarized luminescence is demonstrated in nanosegregated mesophase comprising only achiral molecules. An achiral molecular mixture of a bent‐core host and a rod‐like guest blended with a fluorescent dye is prepared. Circularly polarized luminescence confirms that the chiral superstructure consisting only of achiral molecules may serve as a chiral super nanospace for inducing chiral emissions from the fluorescent dye that exhibits rod‐like molecular ordering. In other words, the formation of a chiral superstructure by the segregated rod‐like molecules embedded in helical nanofilaments (bent‐core molecules) is confirmed. The results provide a novel strategy for constructing dissymmetric circularly polarized luminescence materials based on achiral molecules, which is potentially applicable in future information and display technologies." @default.
- W2950106438 created "2019-06-27" @default.
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- W2950106438 date "2019-06-11" @default.
- W2950106438 modified "2023-10-17" @default.
- W2950106438 title "Circularly Polarized Luminescence Induced by Chiral Super Nanospaces" @default.
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- W2950106438 doi "https://doi.org/10.1002/adfm.201903246" @default.
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