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- W2950115570 abstract "Four groups of flash vacuum pyrolytic reactions are proposed as being useful in synthetic organic methodology: 1,2and 1,4-eliminations; fragmentations of carbonyl compoundn; Diels-Alder and retro-Diels-Alder reactions; acetylene methylenecarbene rearrangements. INTRODUCTION Pyrolytic reactions must have some virtues; there has after all been a flood of papers on flash vacuum pyrolysis (FVP) in the chemical literature of the last 25 years. These virtues have, however, rarely shown up in the area of multi-step synthesis. Instead FVP has mostly been used for the generation of small, highly reactive or transient molecules such as 1 6. The pyrolytic generation of 1-methylpentalene 1 (ref. 1) is clearly one of the chemical triumphs of this century, but it contributed more t o the theory of aromaticity than to synthesis. In the context of the present Symposium my rhetorical title question must be re-defined to ask whether pyrolytic methods can usefully be added to standard synthetic methodology." @default.
- W2950115570 created "2019-06-27" @default.
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- W2950115570 date "2010-08-23" @default.
- W2950115570 modified "2023-09-26" @default.
- W2950115570 title "ChemInform Abstract: Are Flash Pyrolytic Reactions Useful?" @default.
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- W2950115570 doi "https://doi.org/10.1002/chin.199105352" @default.
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