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- W2950132227 abstract "A partir des enynes 8 et 10 une cyclisation de type 6-endo-trig a ete realisee par action de Bu 3 SnH/AIBN, conduisant a la preparation du systeme AB trans decalinique de la (±)-forskoline 1. Dans une seconde approche de la (±)-forskoline 1, le diol 31 a ete oxyde en dialdehyde 6. Un couplage pinacolique a ensuite ete obtenu par traitement du dialdehyde 6 avec SmI 2 et a conduit au derive 6β,7β-diol 41. A partir de ce dernier, la lactone insaturee 2 a pu etre preparee, nous permettant ainsi de realiser une synthese formelle de la (±)-forskoline 1." @default.
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- W2950132227 date "1997-01-01" @default.
- W2950132227 modified "2023-09-25" @default.
- W2950132227 title "A synthetic approach to (+/-)-forskolin. Part II. Radical approaches of the AB ring system and formal synthesis of (+/-)-forskolin" @default.
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